X射线光电子能谱(XPS)2

1、II(XPS)TOC o 1-5 h z HYPERLINK l bookmark2、XPS3X3341Koopman67JO1213 HYPERLINK l bookmark30、XPS(GeneralFeatures)14 HYPERLINK l bookmark40XPS14XPS17、18:.18193、21、26 HYPERLINK l bookmark58、XPS301、(UHV)30 HYPERLINK l bookmark622、X303、314、335、336、347、348、35 HYPERLINK l bookmark28、XPS361、362、36 HYPERLINK

2、l bookmark703、XPS(iXPS)37、38、39(ElectronSpectroscopy)X(XPS)2_ #2 ESCA(ElectronSpectroscopyforXPS(X-rayPhotoelectronSpectroscopy)ChemicalAnalysis),X,XPSXPS、XPS(ElectronSpectroscopy)X(XPS)2_ #2 #(ElectronSpectroscopy)X(XPS)2_ #2 #XPS(ESCA),(ElectronSpectroscopy)X(XPS)2_ #2 #(ElectronSpectroscopy)X(XPS

3、)2_ 2 #:(1)；(3)XPS2.1887(Hertz),19051921PirOTOIONTTAUONOFASINGLEMOLECUT.E吐血寸1AfcrraltttinnhvEk(ElectronSpectroscopy)X(XPS)2_ #2 #(ElectronSpectroscopy)X(XPS)2_ #2 (hvEB),盅硝(1Q+Ek0)，(1)*A+hv4+*+eH硝GTQ-E；2)Ek=hu-Eb3(Primaryprocess)(ElectronSpectroscopy)X(XPS)2_ #2 #(ElectronSpectroscopy)X(XPS)2_ #2 #/

4、eeee光电离A+hv4+*+e()Ek=hv-EB:A,hvo(),9hv=、Eo%n1%()=若咤(2l+1尸(一霸z)P略i+Xi)略+i_:?(f90、9RqkdTOC o 1-5 h zoH、I,ril；l，斤,n/oa：，(ElectronSpectroscopy)X(XPS)2_ 2 #(ElectronSpectroscopy)X(XPS)2_ #2 #10203040506070SO90AtomicNumber(ElectronSpectroscopy)X(XPS)2_ #2 #CalculatedvaJuwofthecrawsectionforAlKalphradiatio

5、nIntermsoftheCiscrossmcEtoii(2)、(secondaryprocess)TOC o 1-5 h z才)，)0 HYPERLINK l bookmark8X()：0 HYPERLINK l bookmark10A+*A+hU(X)()：X+*乂卄*+q_(Auger)(ElectronSpectroscopy)X(XPS)2_ #2 #(ElectronSpectroscopy)X(XPS)2_ #2 #(ElectronSpectroscopy)X(XPS)2 #2 TOC o 1-5 h zb)阳心)(2), HYPERLINK l bookmark34XPS,。

6、XPS,o(n)(n-1()oEb=/(n-1)一EiQq),Eb=,Hartiee-Fock(HF-SCF)。衬J什訂巧+工则制+工(2厶一瓦)弋+工(2厶一瓦)MjjKoopman99oKoopman,(SuddenApproximation)。， HYPERLINK l bookmark46oN-l1=11J=1E，=f成+f(2厶-瓦)-f(2心-心)2=1ij=li=lEB=Ef-El=-Sqk-f(2丿迖-心)=-农2=1Koopmans。Eb10-30eV,Ebo(ElectronSpectroscopy)X(XPS)2 2 #(ElectronSpectroscopy)X(XP

7、S)2 #2 #200100000900800700600500400300200100(A巴gcao(ElectronSpectroscopy)X(XPS)2 #2 01020304050Z607080901002.Eb=一E何，Ebo9,EboEbAEbEb8eVoAEb=血Eb0Al(0,Ab)，2p072.7eV；A12O3,Al+3,2p747eV,2eVo-2(Na2S)-H5(Na2SO4)SIsEb(Cu、Ag)XPSXPSoCis(ElectronSpectroscopy)X(XPS)2 2 #(ElectronSpectroscopy)X(XPS)2 #2 #(Electr

8、onSpectroscopy)X(XPS)2 #2 #(ElectronSpectroscopy)X(XPS)2 #2 #TOC o 1-5 h zCis:C-CC-OC=OO-C=Oo；S0；n=2.90=0。?=3OIX(XPS)X(XPS)2 #2 #ohlX(XPS)X(XPS)2 #2 #X(XPS)X(XPS)2 2 #|Xi-X/-|1X(XPS)X(XPS)2 #2 #X(XPS)X(XPS)2 #2 #X什1)=X(Z)+%X(Z4-1)-X(Z)X(-1)=X(Z)+%X(ZH-1)-X(Z)X(XPS)X(XPS)2 #2 #X(XPS)X(XPS)2 #2 #a).Eb

9、b)EbLXX(XPS)X(XPS)2 #2 #(Groupshiftmethod)(ElectronSpectroscopy)(ElectronSpectroscopy)2- #2- 3Eq=Ej(n-1)EI(n),(Shakeup)(Shakeoff)XPS(ElectronSpectroscopy)(ElectronSpectroscopy)2- #2- #(ElectronSpectroscopy)(ElectronSpectroscopy)2- #2- #XPSXPS(intra-atoniicterm)(1).o(extra-atomicterm)99叽=叱+E；囂】K=Io+E

10、relaxo)9XPS9()(一氐)o(=一=另厶另，KoopmansIk()，oXPSO(2).()XPS(ElectronSpectroscopy)(ElectronSpectroscopy)2- #2- #(ElectronSpectroscopy)(ElectronSpectroscopy)2- #2- #ILl|L0(ElectionSpectroscopy)X(XPS)2- 2- #(ElectionSpectroscopy)X(XPS)2- 2- 4厶=1/一厶=0,l，土2,AS=土(2TOC o 1-5 h zI0D=l,S=l/2,XPS9999 HYPERLINK l b

11、ookmark68XPSo9LSo(2S4-1),S0彳S+%)_s+l何%厂(4f)4s)3s(3).X920%。(Shakeup)：(Shakeoff)o,kistNs,npirip,9A7=AZ=AS=Oo9,XPS:3一GkibcsIlo沪apMl检gands?)evp心才*2#2旳inpsrtBQffiCrf8DJamA.tdfnHa.卩34*1DiimegnelicSlato22TI.Tr*n*423V*524Crt2fOti,Ot4!CrCr*e2SMntJ.Mn*3tMnf4.Mn*5Mn，26讥.Ft2F色(CN.Fe(COhBfj27Co*s.Co3COB.CotNOjhC

12、NHi.K3Go577期“92uWuCii/CuO/CiiOCu2p3/2p/c,CuCmOCuO4XPS0Figure8Examplesofshake*uplinesobservedwiththecopper2pspectrum.HE；hvE；HFenniFemiiFermi昭乞-(-JE；=hv-Ek-%=hv-E：-jE；=Eb0hvO光电子A动能fEvEf结合能(1)(1016s)：(2)(3)昴+加,(4)(5)QC-ray)(6)(7)(8)(9):b(1s)b(2s)B(2p)Eb(3s).Z:(NaIs)B(MgIs)Afmraik)Airrmlk)1:22；33:4&s-XP

13、Sbpdf-XPS&JEb(屁2pl/2屁2p3/2)bZb-()(5).X-(ElectronSpectroscopy)X(XPS)2- #2- #(ElectronSpectroscopy)X(XPS)2- #2- XPSC2s10Ethane*-Vn-Noncnen-C9H20C2p空“71510ProDCneC3%T2tub一30252CEC2SBindingenergy(eV)rel.vacuumlevel252C1519530252015105Bindingenergy(eV)rel.vacuumlevel(ElectronSpectroscopy)X(XPS)2- 2- #(El

14、ectronSpectroscopy)X(XPS)2- #2- 2.XPSXX:2p3/2TlS2pgTsKg()MgAlKgA，hvATai,29-10eVoK/3XoX,X()oXXPSa”oX(X-raysatellites).XPS,X(shake-uplines).oCls(7r7t*)=291.7eV(multipletsplitting).Soiv.()(energylosslines).4,(皿)oBINDINGENERGY,eVFigure12.Energyloss(plasmon)linesassociatedwiththe2slineofaluminum(a=15.3eV

15、;notesurfaceplasmonatb).(ElectronSpectroscopy)X(XPS)2- 2- #TOC o 1-5 h zX,0liun5miloO9 HYPERLINK l bookmark26XPSoXPS、()、(ElectronSpectroscopy)X(XPS)2- #2- #(ElectronSpectroscopy)X(XPS)2- #2- #:XPS(ElectronSpectroscopy)X(XPS)2- #2- #(ElectronSpectroscopy)X(XPS)2- #2- #(1).(Surveyscan)XPS01200eV,co；:p

16、,d,f(ElectronSpectroscopy)X(XPS)2- #2- #(ElectronSpectroscopy)X(XPS)2- #2- MgKaAlKa(2).(NarrowscanorDetailscan)(ElectronSpectroscopy)X(XPS)2- 2- #(ElectronSpectroscopy)X(XPS)2- #2- #(ElectronSpectroscopy)X(XPS)2- #2- #from275eVupto300eV口from675eVupto700eV(ElectronSpectroscopy)X(XPS)2- #2- #(Electron

17、Spectroscopy)X(XPS)2- #2- #2.XPS(ElectronSpectroscopy)X(XPS)2- #2- #(ElectronSpectroscopy)X(XPS)2- #2- #(Photoelectronlinechemicalshiftsandseparations).eV)(ElectronSpectroscopy)X(XPS)2- #2- #(ElectronSpectroscopy)X(XPS)2- #2- #Cis：TiC(281.7eV),XPSNMRH、He(284.3eV),CO2(297.5eV)oCH,XPS(ElectronSpectros

18、copy)X(XPS)2- #2- 11parameter).XPS1003000eVXXPSAESoC.D.Wagiier1972XPSXPS(AugerlinechemicalshiftsandtheAuger(ElectronSpectroscopy)X(XPS)2- #2- #(ElectronSpectroscopy)X(XPS)2- #2- #。a三尿(必)+EbQ)(Shakeuplines)(ElectronSpectroscopy)X(XPS)2- #2- #(ElectronSpectroscopy)X(XPS)2- #2- #XPS(ElectronSpectroscop

19、y)X(XPS)2- #2- #(ElectronSpectroscopy)X(XPS)2- #2- #CisfMultipletsplitting)(Augerlineshape),KW、LW、LMV,o,XPSIRNMRo、(ElectronSpectroscopy)X(XPS)2- 2- #(ElectronSpectroscopy)X(XPS)2- #2- 3、(CaseStudy)、(polymer)C、O、N、S(i)CisC9(C-C)H(C-H)Cis285eV。()OH,c-oCis1.50.2eVoc-o-xX(X=NO2)住0.4eV)：X=NO20.9eVoHaloge

20、nPrimaiyshift(eV)Secondaiyshift(eV)F2.90.7Cl1.50.3Br1.0一OCONH-、-CONH2oNls-ONO2(408eV).-NO2(407eV).-ONO(405eV)oS2pCis(5.4eV),S2p:RSR(ul64eV),R-SO2-R(167.5eV),R-SO3H(169eV)、【】(1):Fe,Cr,Ni,:(1lOOOeV),:999OTOC o 1-5 h z,Cn8Nii43Mo25500C0.5、5XPS,Cr,Mo,(ElectronSpectroscopy)X(XPS)2- #2- (ElectronSpectrosc

21、opy)X(XPS)2- #2- #Cfo(ElectronSpectroscopy)X(XPS)2- #2- #(ElectronSpectroscopy)X(XPS)2- #2- #(ARUPS)Eg)oSCHOTTKY-BARRIEREk.XPSXPS6,4、(ElectronSpectroscopy)X(XPS)2- #2- #(ElectronSpectroscopy)X(XPS)2- #2- #Et=Ej-hv(ElectronSpectroscopy)X(XPS)2- #2- #Im+hv)sin82mcos2+/?k-/?u0)(ElectronSpectroscopy)X(X

22、PS)2- #2- #(ElectronSpectroscopy)X(XPS)2- #2- #hvhv0=5.6eV0(a)IiiSb(OOl)=11.83-40.82eV,(ElectronSpectroscopy)X(XPS)2- 2- #(ElectronSpectroscopy)X(XPS)2- #2- #(ElectronSpectroscopy)X(XPS)2- 2- 5、Trouble-shootingapplications;Wliyhasaparticularmaterialstoppedworkingeffectively?Correlationofsurfacecompo

23、sitionwithcatalyticperfonnance;FurtheringthescienceofcatalysishiterpretationofXPSdataintermsofthesizeofsupportedciystallites,XPSoXPS、09oXPS9090XPS009oXPS9900199n9I宀T.勺?,（：）/%（E）c8&d二.:IijIJ,K,T(E)，心（7）iJ，/J，坷（二）I,eoX、9oo，YX,X:34”1一扣(3cosl)Pl=，yXo0=54.7(magicangle),3cos2y-l=0,厶刈)。厶)(y)90o(FirstPrinci

24、pleModel)9H9H99920(）。切=KT(E)4(力42(E)cos0,q=切/KT(E)4(力吟心cos0=IJSv.S尸疋T)(y)乌Xfcos%TS(7)p矿九，o/ls=lo慣=Itj!Sij，!八可号【1】j：4_I屆勺1屆15%。5%o()2%0&hHeXPSXPS)0A(omicnumber|9io|PHIsensitivityfactor拿fordesignatedphotoelecirooiransitionElementsymbolIpMoseinrensephotoelecctoniranMtionIA(omintenseAugerirunMiion|KLLHe

25、ITsS85IBindingenergy,mostincensephotoeketrontransitionIKLL647IKineticenergy.nxs(intenseAugertnniiion3ocesLiuw40.C74BetfiH2111.S85Na严tma妙19(.30K8294脱理371316Rb3din120JS2Mg?pso咚皿201634Ca2p347皿290381.578Sr3d134211.578TX556X)3287Fr566381Ba3d血88Ra2p妙UBA339iO7Y3diMW131577.70BLa3dKg0389Ac221738Ti2PIMUm402.2

26、(6Zr3dinMKV150722221Hf4f23i.e)2Va5UWe412317Nb3dX2SV咽?32.589Taua2?疝knm血252242.201CrMn29574Z血422d67MoM空742.93wXI3!MT41800$36VMM如433266Tc3d253753327Re40NUNm262836Fe2P皿IWTO443696RuW280w.匹763.74727325$Co2pnsIMU7?44S4,?9Rh30W774217ir61EM532836532947580*4册475.iAMMt646460Pd33SkXH3784674Ptt71MSN5Ag3d79528Au3

27、0X354ZnLMSA疏483444Cd3dW4UMMQ805.797Hg410Ga2pX1117y*K.iL493777In3444KW_41t8163Tl4：116KOO鸭60296cis2451402S3Si2pWU4MSO323jooGe2X21217urn卄504.005SnMSN心82段亦Pb&137N00彌70477NU402彰015G.412P2pIXIMM_电330.S70As3d42514473Sb3dw523MMN8Q711ois53!160570se$3407W3dLUM1X652详5Te咖573837T84Bi1ts?N8KMPo91.0FW8SKU血170770Cl

28、19635owsBrMWMKV35353373JM6Ti8FAt101340Neis曲KU.细18tonArIMM2巧36ioeKrM9f54sToeXeUM54586Rn58Ce3d妙59ewePr3d532*锄60467NdWtl729613754Pm301CMMMM773622307Smg1081MhNKA632210Euuw曲64awGdd140MMNB665220$TbM146WMMW662.196Dy4dt52MW1113672.isoHo4d160UW冯682心Er4d0MT1214692.172Tm4d175702.160Yb1C2712.156Lu790?Th加333qa91

29、Pa928.476U4(rt87MDV7593Np94Pu95Am96Cm7Bk98Cf99Es100Fm101Md102No103Lr),:dlML(ElectronSpectroscopy)X(XPS)2- #2- #(ElectronSpectroscopy)X(XPS)2- #2- #S=SI九(ElectronSpectroscopy)(ElectronSpectroscopy)2 2 #SS:n=-0.5,m=1.5oT8E：E；VGESCALABMKII=C-021/og厶Eai021(A=710Hemmingerlog3.(ElectronSpectroscopy)(Elect

30、ronSpectroscopy)2 #2 #(ElectronSpectroscopy)(ElectronSpectroscopy)2 #2 #:(1)X;(2)(ElectronSpectroscopy)(ElectronSpectroscopy)2 #2 #(ElectronSpectroscopy)(ElectronSpectroscopy)2 #2 #(1)B(ElectronSpectroscopy)(ElectronSpectroscopy)2 #2 #(ElectronSpectroscopy)(ElectronSpectroscopy)2 #2 #COS0COS0(Electr

31、onSpectroscopy)(ElectronSpectroscopy)2 #2 #(ElectronSpectroscopy)(ElectronSpectroscopy)2 #2 #【A=(ElectronSpectroscopy)(ElectronSpectroscopy)2 #2 #(ElectronSpectroscopy)(ElectronSpectroscopy)2 #2 dA；5=/exp_右/nvcrfAyVuiHimic11(ElectronSpectroscopy)X(XPS)2- 2- #“皆一叫飞）丿IdA1-expI人(巧)cos。丿】b&Zexp_IAfWJcos

32、O丿oAA(EA(B)，(ElectronSpectroscopy)X(XPS)2- #2- #(ElectronSpectroscopy)X(XPS)2- #2- ：AlKclX0.711odA右cosOln1+,CIsOIsEk,AEd，,c/o0.296,OIsEb(eV)Cis285.02000Cis286.6700Cis289.0700Cis291.6100Ols532.11600Ols533.71685Ols538.785oCIs1c/(2000+700+700+100)/c/%296(1600+1685+85)/0.711-2.5=-2C:C:C:O:O=3:1:1:1:1:Cj

33、HioO?ch3oIIICH3COCHCH3CH3-CH2-CH2-CH2-O-CH=O(ElectronSpectroscopy)X(XPS)2- 2- #(ElectronSpectroscopy)X(XPS)2- #2- #、XPSVGESCALABMKD(ElectronSpectroscopy)X(XPS)2- #2- #(ElectronSpectroscopy)X(XPS)2- #2- #(UHV)(ElectronSpectroscopy)X(XPS)2- #2- #(ElectronSpectroscopy)X(XPS)2- #2- #,IX10smbaro；(2)+;(3)

34、+oESCALABMKH:(1)+:(4)o()(ElectronSpectroscopy)X(XPS)2- #2- #(ElectronSpectroscopy)X(XPS)2- #2- lX1010torro2、X(1)X:XPSXoXoMg/AlX,XMgKahxl253.6eVAE=0.7eVAlKahv=1486.6eVAE=0.85eV卜莎iDouhk.nru!teX-raysounoe.(ElectronSpectroscopy)X(XPS)2- #2- #(ElectronSpectroscopy)X(XPS)2- #2- #1-3：(2)(10eVlOkeV),02eV,3、

35、(eV)FWHM(eV)(eV)FWHM(eV)YM13230.47MgKa1253.60.7ZrM151.40.77AlKa1486.60.85Nb171.41.21SiKa1739.51.0MoMg192.31.53YLa1922.61.5TiLa395.33.0ZrLa2042.41.7CtS572.83.0AgLa2984.42.6NiLa851.52.5TiKa4510.02.0CuLa929.73.8CrKa5417.02.1NaKa1041.00.4CUKa8048.02.6(FWHM)(ElectronSpectroscopy)X(XPS)2 2- (CHA)(CMA)Fica

36、rr.SchritwutKtw&-vrliunrfmruMTiiiritbrtiihpixrirulnulsxrfCIIA)09ER990肚2禺ed%AooROy尺1尺2旳卩2o(CAE)(CRR)oCAE9Eq,E_sE2氏oo(FWHM)=0lLOeVX,FWHMtotai=(FWHM2x.ray+FWHM2imldth+FWHM2Miaiysei)1/20.7-1.0eV90,XPS(AES,ISS,SIMS,LEED,EELS)oPemiing0VGAG61,6、九）hv1、2、.(II).(m)(ElectronSpectroscopy)(ElectronSpectroscopy)2

37、- #2- Ep，(TV).Tougaard1983TougaardBqIOS10410210098BindingEnergy(eV)30eV,D=AP!BX(XPS)X(XPS)2- 2- #X(XPS)X(XPS)2- #2- #X(XPS)X(XPS)2- #2- #X(XPS)X(XPS)2- #2- #3、XPS(iXPS).XPSX(XPS)X(XPS)2- #2- #X(XPS)X(XPS)2- #2- X(XPS)X(XPS)2- #2- X(XPS)X(XPS)2- 2- #XPS1960oXPSoXPSXPS(HHe)XPS0.1%(H,He)；(v土10%),9120(7

38、1*)9“10nm,(1)XPSlOiun,XPS):(2)(；x5150|un,、XPS,XPS、XPS1.922.XPS?XPS?3.X4.XPS9(sax)XAppendixG.LinePositionsbyElementforAlKaX-rays(Electronspeccroscopy)UMUsM.KLuLAugarLincsKIhU)KLiLiAtomicumber/Elmen(PhmekclroDUmslItZps2pg3spwi3p衍3dsSdg為4ps4pv)3MJ3I0)22311079783266993501LzMTc1?)10138?S85972$TOE乂）53238M

39、762K559474)23362J7分719需5MMuXUNn299旳1390S38JM4fNDV13%1368-稈5816212428152J5139威92697訂345679-24s6*T11扌一304)57?0繍山36说凶,9IJ1222239693738307223344566仃陰总黑鸳蠢34s0u7455196s32ol9234og8ta5J2568725l6omr3o1234S5&78GF11uBeBCNopNeNaMAIslpsaArKascTivCTM.FCezcNCGeASseBrKZRbsrYzr345b?A9m订门DMl516门IS

40、19202122232425262722930,32幻乂孙比幻33940(sax)X(sax)XLinesenclosedinboxesaretheonuswhichar匕mosusefulforidentifyingchemicalstates.IncludesKVVdcsignauonwhenL23isnotacorelevel.Dwignaiionisoversimplified.IncludesLWwhenMlevelsarenoincoreandMWwhenNlevelsarcnotincore.Nosimple4pi/j.lineexistsforthisgroupofelemen

41、ts.0The4*oaNumber/ELrmerW3HU33n3d3PSJpyzS3fcsBsdpv:4pyjvz4d4f*25sspsSP5浚s5dr於q昊8歹孑吕匕总现孑日诸民孑总才父营事孑咅卫介匚51点挈堂孑2當卫弓召点暫聂一一一55gggWg豪善弐23空誉总盒占台玄一一98,7、40.SF4*U4-VIistfa-SStaaasdiSKUfSJ1J842SS|S|3?!SsSS3?cn3si7?一一=9Q89C7y664pJyy養詐养瓷昭灯沙“崔甘玮貉舁獺貓沦谜魚汕姑谿玮和殆龄汕冠菇订汕爰兰曲汕目转影潍昶曲淞轴詐壬応拥站航注號転沙3旅目辭席騎曲沙善辭注龄狛鹽汕汨6菇花奈空沁从攵f63孤

42、壮豁游样竝汕別沙站最_汀沁缶sosasa&fettaStJs厶57-淞獺約潞轴圾弐恥淞捕泻88Sii-54444蠱3=Qt765金3ZW7tiS3la料3出；2團=1-&-口4F总虽弓禺ERW月电堂gggSSiSnotW35B32Sm*Srss3S2S5：tisySittKii=訐汕siSsas22525(sax)X(sax)XCM3-CIM2VM$N45N4/M2gM2gvM_vvM4Vg*zg仝2t1岸g壬5Ew5扶E3UJKg*sf3Bg5gi弓|2XK?ofto&Z5(sax)XAppendixH.LinePositionsbyElementforMgKaX-rays-(Electro

43、nspechoscopy)LM4sM4W，AutrLiKLiLuKUsLjKULiAComkNuiwUtf/tkrneelPhofodZb&hUnoU2p.v?kMviMw40avx心315E159773953262S4179?MI766M5626J924252W148IUMMlAl#fj*LiASuMefVl9560654447941533455677B9l-*tLBeBCNOFNCNlMeAIhpsuATKCKXTIvaMIIFedNIdzndGeASseBfKfRbsrYzf34s划3$9101112nM)5mHl&l920212223M252627M29x)3l3233M5536pMS

44、;40Lincsenclosedioboxesareibeoneswhicharemostusefulforidentihmgchemicalyaies.IncludesKWdesignationwhenL23isno6p3S5孕一3口234&82秣厂”2&一_kSS5SsSSSE匕以二二总缁裁泻紅北弐曲淞汕泻(82-5444*4整33一一00765“27uxafeyfiaaaiissi占2“32i9g9766VSlzs444-34U匕么2冷$()!吕呂毛匕5071329瓜39100986*-570022忖98缸43它主33匕g里JJSS738b石2巴aS3ftCjmS3K3Socm$Z忖22229QA：l633丘巴皆22工总思30*353忘477374544MJism兰兰储geiNSNiTNi-off】089_W3ilclIKK=9二3一MSKxsU79玄涎荽024N7N73_07507637K08-i二03三0=2-?c-OS97?o0-4s匸i33匕44SSS