有机化学-试题库(完成转变)

1、按指定原料合成以下化合物无机试剂、苯及两个碳以下含两个碳的有机物任选CH3CH 二CH2 CH3CHCOOHCH2COOHCH3CH 二CHCHOOHCH3CHCHCHO OHCH3LC CH2CH3OHCH2CH3CH3BrOHCOOHBrNO2CH=CHCOOHCH 3CH=CHCHOch3chch 3HO-CHCH 3H2NCH2CH2CH2CH2NH2CH2CH2CH2CH34h2nch 2ch2ch2ch 2nh 2ch2ch2ch2ch3ch3ch2ch=ch 2 ch3ch=chch 3ch2=chch=ch 2CH2OHCH2=CHCH=CH 2OHCHPhch2=chch=c

2、h 2OHCHPhH3CHC0OCHCH30J。CH2=CHCH=CH 2PhCH2CH2COOHNH2H2 n COOC 2 H5H2NkOHCH 3CH 2=C PhCH 3CH3CHCH -CH3(CH2)6CH31.CH2. ch3chcoohch2cooha) NaCN/ b)H 3+O CH3CHCH2Br1BrOHCH3CH 二 CHCHOCH3CHCHCHO5.6.CH 3CH 2Br8.COOH9.10.H2NCH2CH2CH2CH2NH2a) KMnO 4b)NH3/ 色CH3CH=CH2 CH3CHCH3HOCHCH3a) HBrb) Mg/无水 Et2O,./a)CH3

3、CHOCH3CHCH3b) H3+O1MgBrNH2CO(CH 2)4CONH213.14.15.CH2CH2CH2CH3CH3CH2CH2COCIa) KMnO 4b) SOCI 2CH3CHO稀N叫 CH3CH=CHCHO 空CH3CH2CH2CH2OHCH3CH2CH=CH 2 CH3CH=CHCH 3a)KMnO 4b)NH 3/厶I c)Br2/NaOH厂*NH2NaNO 2/HClNClOCH 2COOH17.a) NaNO 2/HCICH3CHOHCHOCH2=CHCHOa) Fe/CI 2a) NaOHb) 混酸b) dCHzCOOHc) Fe/HCINaOH18.Q 

4、7;CH31/AQ13厂CH3Cl2/hv -OLhCH3CCHCH 2PhCH 3厂5Tch2ciCH3CH2OHCH3COOHH +CH3COOC 2h5NaOC 2H5O11ch3cch 2cooc 2h5O iCH3CCHCH 2PhCH 3a) NaOC 2H5b) PhCH 2CI*c) H3+Oa) NaOC 2H5 ,b) CH 3IOCH 3CCHCOOC 2H5CH 3浓 NaOHHCHO(HOCH 2)4CCH3CHO/HCIH3CHCCHCH 3OJ。HCHOCH3cHO稀NaOH (HOCH 2)3CCHOH3CHCOOCHCH 3OJ。20.PhCHzCHzCOOH

5、a) CH3I/AICI3b) Fe/CI 221.CH2CICICH 2COOHa) NaCNb) H3 O+c) CH3CH2OH/HCOOC 2H5H2CCOOC2H5a) NaOC 2H5b) PhCH 2CI+c) H3 OPhCH2CH2COOHN=Na) 混酸b) Fe/HCIaNH2 a) NaNO 2/HCITMb) PhNH 222.CH2=CHCH=CH 2CH2=CHCOOC 2H5H2N COOC 2H5H2NNH3XCOOC2H5Br2BrCOOC 2H5BrsOHI23. CH3CH2C三CC -PhCH3CH3COCI/AICI 3a) Na/NH 3厂计-COCH 3b) CH 3CH 2C三 CH*a) Na/NH 3CH 3CH2C= CHHC 三CH -b) CH 3CH2Br25.CH3(CH 2)6