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1、(19)TEPZZ 789454A TEP 2 789 454A2(11)EUROPEAN PATENT APPLICATION(12)(43)(51) Int Cl.:B29C 70/88 (2006.01)Date of publication:15.10.2014 Bulletin 2014/42B29C 70/24 (2006.01)(21)Application number: 14162743.0(22)Date of filing: 31.03.2014(54)A method of through-thickness reinforcing a laminated materi

2、al(57)A method of providing through-thickness rein-through-thickness reinforcement is required and a step of inserting a reinforcement element (140) through the thickness of the laminated material at the location of the locally heated zone to through-thickness reinforce the laminated material.forcem

3、ent of a laminated material (100) which includes a matrix material (130) including a step of creating a lo- cally heated zone (180) in the laminated material so as to locally soften the matrix material by focussing a set of at least two energy beams (160) at a location wherePrinted by Jouve, 75001 P

4、ARIS (FR)EP 2 789 454 A2(84) Designated Contracting States:AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TRDesignated Extension States:BA ME(30) Priority: 10.04.2013 GB 201306479(71) Applicant: Rolls-Royce plc London SW1E 6AT (GB)(72)

5、Inventor: Jevons, MatthewDerby, Derbyshire DE24 9ES (GB)(74) Representative: Hill, Matthew Ross et al Rolls-Royce plcPO Box 31Derby, Derbyshire DE24 8BJ (GB)1EP 2 789 454 A22Descriptionshows how this can be achieved by heating the pre-im- pregnated laminated material enough that the reinforcing fibr

6、es can be inserted through the softened matrix mate- rial. It can be seen from Figure 6 that, by heating the laminated material, the dynamic viscosity of the epoxy resin will be considerably lower than at room tempera- ture. This reduction in viscosity greatly aids the process of inserting the reinf

7、orcing fibres.0010 However, the heating process presents chal- lenges as, usually, many thousands of reinforcing fibres are required in order to manufacture a suitably strong composite component.0011 One option is to heat the pre-impregnated lam- inated material just enough that the matrix material

8、does not reach its gel point. The gel point is the temperature at which the curing process begins and the matrix mate- rial will begin to harden. The gel point is shown in Figure 6 as the inflection point of the rheology plot, i.e. the point where the reduction in viscosity induced by heating ceas-

9、es and further heating causes a rapid increase in viscosity as the material starts to cure or harden. Once begun, the curing process cannot be reversed.0012 Keeping the matrix material below its gel point may be achieved by cycles of heating and cooling the laminated material as the many reinforcing

10、 fibres are in- serted. This need to keep the laminated material cool enough adds considerable time and complexity to the manufacturing process. It can also therefore, be a proc- ess which consumes a large amount of energy. Taken alone, the process of heating the laminated material so that the matri

11、x material is uniformly softened can be time consuming.0013 Another option is to heat the pre-impregnated laminated material to a known temperature having a cor- responding known and finite time-interval until the matrix material reaches its gel point. Once this temperature is reached, all the reinf

12、orcing fibres, which are to be insert- ed, must be in place before the matrix material begins to harden. It follows that, by reinforcing the laminated ma- terial in this way, there is limited scope for correcting pro- duction errors in the insertion process as once begun the curing process cannot be

13、 stopped.0014 What is needed is a process where the reinforc- ing fibres can be inserted in a systematic and timely man- ner, yet independently of the curing process, which in turn can then remain uncompromised by the insertion of the reinforcing fibres.0015 According to an aspect, there is provided

14、 a method of providing through-thickness reinforcement of a laminated material. The laminated material comprises a matrix material. The method comprises the steps of: providing a laminated material; and creating a locally heated zone in the laminated material so as to locally soften the matrix mater

15、ial by focussing a set of at least two energy beams (for example two or more than two energy beams) on a focal zone which corresponds to a location where through-thickness reinforcement is re- quired. The method comprises inserting a reinforcement0001 The present invention relates to a method of thr

16、ough-thickness reinforcing a laminated material with a reinforcing element. In particular, the present invention relates to a method of heating a laminated material to insert a reinforcing element.0002 Laminated composite materials, in which rein- forcing fibres are held within a polymeric matrix, a

17、re ex- tensively used in many engineering applications. Such materials can generally provide a higher strength and stiffness per unit weight than conventional metallic ma- terials. This makes such composite materials advanta- geous for weight sensitive applications, such as those in the field of aer

18、ospace.0003 A known problem with laminated composite ma- terials is their poor inter-laminar, or through-thickness, mechanical properties in comparison to the correspond- ing in-plane properties. Such low inter-laminar strength and fracture toughness can constrain the design of com- posite parts and

19、 may even limit the use of such materials for certain applications.0004 One solution to this problem is the use of a toughened matrix material. Such matrix materials are generally significantly more expensive than conventional matrix materials, often have poor high temperature prop- erties and may s

20、till not provide a sufficient increase in fracture toughness.0005 An alternative solution to improving inter-lami- nar strength properties is the insertion of through-thick- ness fibres into the laminated material. Various tech- niques have been developed for the insertion of such reinforcing fibres

21、.0006 One method for inserting through-thickness re- inforcing fibres into the laminated material is stapling or z-pinning. These reinforcing fibres are generally fibrous in structure and may be formed with a 45 chamfer at the insertion end. Through-thickness reinforcing fibres are intended to resis

22、t shear forces so as to improve the inter- laminar strength and fracture toughness.0007 The reinforcing fibres may be inserted into lam- inated material which is pre-impregnated with the matrix material. Once the reinforcing fibres have been inserted into the laminated material, the laminated materi

23、al and matrix combination can then be cured in order to form a consolidated composite material. The composite mate- rial may then, with or without further processing, form composite components.0008 Inserting the through-thickness reinforcing fi- bres through the pre-impregnated material is easier, a

24、nd causes less damage to the reinforcing fibres, if the matrix material has an appropriately low viscosity. The viscosity should be such that the reinforcing fibre can be inserted, but that the matrix material surrounding the layers making up the laminated material is retained.0009 Figure 6, which i

25、s a rheology plot (dynamic vis- cosity vs. temperature) for a typical epoxy resin material that might be used in a laminated composite material,51015202530354045505523EP 2 789 454 A24element through the thickness (for example through at least a part of the thickness) of the laminated material at the

26、 location of the locally heated zone to through-thick- ness reinforce the laminated material.0016 There is also provided a component manufac- tured at least in part using the method of providing through-thickness reinforcement of a laminated material. 0017 The use of at least two energy beams may al

27、low the strength of each individual beam to be set at a level that, on its own, would not sufficiently heat and/or soften the laminated material. Thus, in regions that are only ex- posed to one of the energy beams, the laminated material may not be heated sufficiently to be significantly softened an

28、d/or such regions may remain at a temperature signif- icantly below the gel point/curing temperature.0018 In this way the volume of the laminated material that is heated is minimised. This reduces the amount of energy required to through-thickness reinforce the lam- inated material. Additionally, a

29、significant time saving can be made during manufacture. The need to provide heat- ing and cooling cycles for the laminated material is min- imised or eliminated altogether. The insertion of the re- inforcing elements may be achieved entirely independ- ently of the final curing process necessary to c

30、reate the ultimate composite material. Furthermore, local heating lessens the likelihood that the gel point of the matrix ma- terial is inadvertently reached during the insertion of the reinforcing element, which would cause the matrix ma- terial to prematurely harden.0019 The focal zone at which th

31、e at least two (that is, two or more) energy beams are focussed may be referred to as a focal point.0020 The method of through-thickness reinforcing a laminated material may have any one of or, to the extent that they are compatible, any combination of the following features.0021 The reinforcing ele

32、ment may be formed from the group comprising boron, carbon, glass, silicon car- bide, aluminium oxide, aluminium nitride, rigid phenolics, rigid polyimides, rigid epoxies, metal, nylon and compos- ites of such materials.0022 The reinforcing element may be formed from a material which is compatible w

33、ith the matrix of the lami- nated material.0023 In one embodiment of the invention, the rein- forcing element is formed as a parallel sided cylinder or fibre. In other embodiments, the element may have other geometries such as, for example, a tapered or other shaped cylinder and/or may be fluted or

34、ribbed.0024 The step of creating the locally heated zone in the laminated material may be by focussing a set of more than two energy beams on the focal zone. This may allow the energy of each individual energy beam to be reduced still further.0025 The energy beams may be emitted from energy beam emi

35、tters.0026 The step of creating the locally heated zone may include creating an array of locally heated zones by fo-cussing a corresponding array of sets of energy beams on a corresponding array of focal zones at locations where through-thickness reinforcing is required and the step of inserting a r

36、einforcement element may include inserting a plurality of reinforcing elements through the thickness of the laminated material at the locations cor- responding to the array of locally heated zones.0027 Any suitable number of reinforcing elements may be inserted into the laminated material. For examp

37、le, many thousands of reinforcing elements may be inserted into the laminated material.0028 The array of sets of energy beams and the cor- responding array of focal zones may be arranged linearly in a row.0029 The method may include a step, which follows the step of inserting of the plurality of rei

38、nforcing ele- ments, of translating the laminated material relative to the array of sets of energy beams and the corresponding array of focal zones to another set of locations where through-thickness reinforcing is required. Thus, another set of the reinforcing elements may then be inserted into the

39、 laminated material. The process can then be repeat- ed any suitable number of times to insert the required reinforcing elements (of which there may be many thou- sands, for example) in the laminated material.0030 The step of creating the locally heated zone in the laminated material may comprise fo

40、rming a full-thick- ness heated zone that penetrates through the entire thickness of the laminated material.0031 The method may include the step of forming a hole in the locally heated zone in the laminated material and then performing the step of inserting the reinforcing element by inserting the r

41、einforcing element into the hole. The hole may be formed by a needle.0032 The steps of creating the locally heated zone in the laminated material and inserting the reinforcing ele- ment through the thickness of the laminated material may be performed at substantially the same time. Where a step of f

42、orming a hole in the locally heated zone in the laminated material is employed, this may be performed at substantially the same time as creating the locally heat- ed zone. The heating process may be started and stopped slightly before or after the inserting process, for instance depending on the nee

43、d for effective insertion of the reinforcing fibre. For example, the heated zone may be formed slightly prior to commencing the insertion of the reinforcing element.0033 The reinforcing element may have a tip and the step of creating the locally heated zone in the laminated material may include the

44、focal zone tracking the tip of the reinforcing element (or, where used, a hole-forming tool) as it is inserted such that the locally heated zone remains ahead of the tip as the reinforcing element is inserted through the thickness of the laminated material. In this way, further manufacturing time sa

45、vings may be made and therefore energy usage is further reduced. With less energy being imparted to the matrix material, the risk of elevating its temperature too close to its gel point is fur-51015202530354045505535EP 2 789 454 A26ther minimised.0034The energy beams may be microwaves. The microwave

46、s may be emitted by microwave emitters 0035The step of creating the locally heated zone may comprise restricting the locally heated zone from reach- ing a temperature corresponding to the gel point of the matrix material.0036 The matrix material may comprise a polymeric matrix material. The polymeri

47、c matrix material may be a thermosetting material, such as an epoxy resin. Alterna- tively, the matrix material may be a thermoplastic mate- rial.0037 The insertion of the reinforcing element may be assisted by hammering. The reinforcing element may be inserted by hammering. The hammering may be ult

48、ra- sonic hammering.0038 The insertion of the reinforcing element may be assisted by rotating or twisting of the reinforcing element. 0039 The method may include the step of curing the through-thickness reinforced laminated material to form a composite material. The curing may be by heating the lami

49、nated material to its gel temperature in order to cure the matrix material and consolidate it into a composite material.0040 Any suitable curing technique may be used. For example, a conventional curing technique may be used. By way of example, the curing may be ultra-violet curing, autoclave, or ou

50、t-of-autoclave curing.0041 The manufactured composite material may be utilised to form a gas turbine engine component. The manufactured composite material may be utilised to form a gas turbine engine fan blade. The method may include the step of forming a gas turbine engine component (such as a fan

51、blade) from the through-thickness reinforced laminated material.0042 The invention will now be described, by way of example only, with reference to the accompanying draw- ings in which:Figure 5 shows an example of manufacturing a through thickness laminated material according to the method of the pr

52、esent invention; and5Figure 6 shows a plot of dynamic viscosity vs. tem- perature for a typical epoxy resin used with a lami- nated material.0043 Figure 1 shows an example of a laminated ma- terial 100 comprising a plurality of fibre layers 110. In this instance, each of the fibre layers 110 compris

53、es a plu- rality of uni-directionally aligned fibres 120 held within a matrix material 130. The uni-directionally aligned fibres 120 may comprise tows laid as tape which combine to form one layer. Alternatively, the fibre layers 110 may be woven from fibre tows in the manner of a woven fabric. 0044

54、The matrix material 130 is pre-impregnated in each of the fibre layers 110 before the layers 110 are laid-up to form the thickness of laminated material 100. Once the structure of the laminated material 100 is com- plete the matrix material 130 will be cured so that the fibre layers 110 and the matr

55、ix material 130 consolidate to form a solid composite material. It is expected that the most suitable matrix material 130 will be a polymeric ma- trix material. For example, an epoxy resin is particularly favoured as the polymeric matrix material. However, these matrix materials are given by way of

56、example only, and any other suitable matrix material may be used. 0045 It can be seen in the example of Figure 1 that alternate fibre layers 110 are laid up approximately per- pendicular to one another, but as mentioned above, the fibre layers 110 may comprise fibres having other orien- tations. The

57、 relative fibre orientation of each of the layers 110 together with the quantity of fibre layers 110 may be determined by the design loads to which the finished component is to be subjected.0046 In the example of Figure 1 the fibre layers 110of one orientation lie along the X direction while those o

58、f the alternate orientation lie along the Y direction. In order to through-thickness reinforce the laminated material 100 then a plurality of reinforcing elements 140 need to be inserted in the Z direction. For this reason, through-thick- ness reinforcement may be referred to as z-pinning. Many thousands of reinforcing elements 140 may be re- quired for some composite components manufactured from the laminated material 100.0047 The reinforcing element 140 may consist of a single fibre or parallel sided cylinder. Alternativ

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